MODULE A4

The Periodic Table

From DΓΆbereiner's triads to Group VII halogens β€” master patterns, trends, and reactions in the most useful chart in chemistry! βš—οΈ

Saves the complete Notes tab as a clean, print-ready PDF

1. Historical Development

ScientistYearContributionLimitation/Outcome
DΓΆbereiner1817–29Triads: groups of 3 similar elements where the middle element's mass β‰ˆ average of the outer two. E.g. Li(7) + K(39) Γ· 2 β‰ˆ Na(23)Only worked for a few groups; ignored most elements
Newlands1865Law of Octaves: arranged 56 elements by atomic mass; every 8th element had similar propertiesBroke down for heavier elements; ridiculed by peers
Mendeleev1869Arranged elements by atomic mass; left gaps for undiscovered elements; correctly predicted gallium's propertiesA few elements had to be swapped β€” order not always correct
Moseley1914Arranged by atomic number (proton number) using X-ray experiments β€” this is the modern periodic tableFixed all anomalies in Mendeleev's table
πŸ’‘ Mendeleev's brilliance: He predicted the existence and properties of gallium (eka-aluminium) before it was discovered in 1875. It matched his predictions almost perfectly β€” chemistry's version of predicting a planet before you can see it!

2. Structure of the Modern Periodic Table

Elements are arranged in order of increasing atomic number.

πŸ”‘ Magic Rules:
Group number = number of valence electrons (outermost shell)
Period number = number of occupied electron shells
Example: Phosphorus (2,8,5) β†’ Group V (5 valence e⁻), Period 3 (3 shells)

Key Groups

GroupNameValence e⁻Key Feature
Group IAlkali Metals1Very reactive; react violently with water
Group IIAlkaline Earth Metals2Reactive; form +2 ions
Group VIIHalogens7Reactive non-metals; form βˆ’1 ions
Group 0 (VIII)Noble Gases8 (full shell)Chemically unreactive; full outer shell

General Periodic Trends

DirectionMetallic NatureAtomic RadiusNon-metallic Nature
↓ Down a groupIncreases ↑Increases ↑Decreases ↓
β†’ Left to right across periodDecreases ↓Decreases ↓Increases ↑

3. Group II β€” The Alkaline Earth Metals

Group II: Be, Mg, Ca, Sr, Ba, Ra. All have 2 valence electrons and form +2 ions.

Reactions of Group II Metals

ReactionMagnesium (Mg)Calcium (Ca)Barium (Ba)
With Oβ‚‚Burns with blinding white flame: 2Mg + Oβ‚‚ β†’ 2MgOBrick-red flame: 2Ca + Oβ‚‚ β†’ 2CaOApple-green flame: 2Ba + Oβ‚‚ β†’ 2BaO
With Hβ‚‚OVery slowly; Mg(OH)β‚‚ + H₂↑Vigorously; Ca(OH)β‚‚ + H₂↑Very vigorously; Ba(OH)β‚‚ + H₂↑
With HClVigorously; MgClβ‚‚ + H₂↑Very vigorously; CaClβ‚‚ + H₂↑Violently; BaClβ‚‚ + H₂↑
πŸ“ˆ Reactivity increases DOWN Group II because:
1. Each element has more electron shells β†’ larger atomic radius
2. Valence electrons are further from the nucleus and more shielded
3. β†’ Easier to lose the 2 valence electrons β†’ higher reactivity
Beryllium = least reactive | Radium = most reactive
πŸŽ† Fun fact: Group II metals give fireworks their vivid colours β€” Mg = brilliant white, Ca = brick red, Sr = crimson, Ba = apple green. Next time you see fireworks, you're watching Group II chemistry!

4. Group VII β€” The Halogens

ElementFormulaState (25°C)ColourValence e⁻
FluorineFβ‚‚GasPale yellow7
ChlorineClβ‚‚GasYellow-green7
BromineBrβ‚‚LiquidRed-brown7
IodineIβ‚‚SolidGrey-black (purple vapour)7

Halogen Displacement Reactions

A more reactive halogen displaces a less reactive halogen from its salt solution.

Halogen AddedSalt SolutionReaction?ObservationEquation
Clβ‚‚KBr (aq)βœ… YesTurns red-brown (Brβ‚‚ produced)Clβ‚‚ + 2KBr β†’ 2KCl + Brβ‚‚
Clβ‚‚KI (aq)βœ… YesTurns brown (Iβ‚‚ produced)Clβ‚‚ + 2KI β†’ 2KCl + Iβ‚‚
Brβ‚‚KI (aq)βœ… YesTurns brown (Iβ‚‚ produced)Brβ‚‚ + 2KI β†’ 2KBr + Iβ‚‚
Brβ‚‚KCl (aq)❌ NoNo colour changeNo reaction
Iβ‚‚KBr (aq)❌ NoNo colour changeNo reaction
πŸ“‰ Reactivity / Oxidising strength increases GOING UP Group VII because:
1. Fewer electron shells β†’ smaller atomic radius
2. Valence shell is closer to nucleus with less shielding
3. β†’ Atom attracts extra electron more strongly β†’ easier to gain 1 e⁻
Order (weakest β†’ strongest): I < Br < Cl < F

5. Trends Across Period 3

Period 3: Na, Mg, Al, Si, P, S, Cl, Ar β€” all have 3 occupied electron shells.

ElementConfigTypeReactivityAtomic Radius trend
Na(2,8,1)MetalMost reactive metal (loses 1 e⁻ easily)Decreases β†’
(more protons pull electrons closer)
Mg(2,8,2)MetalLess reactive than Na
Al(2,8,3)MetalLeast reactive Period 3 metal
Si(2,8,4)MetalloidSemiconductor; shares electrons
P(2,8,5)Non-metalLeast reactive Period 3 non-metal
S(2,8,6)Non-metalMore reactive non-metal
Cl(2,8,7)Non-metalMost reactive Period 3 non-metal
Ar(2,8,8)Noble gasUnreactive β€” full outer shell
πŸ–₯️ Silicon β€” The Backbone of the Digital Age: Silicon's semiconductor properties make it ideal for transistors. Every computer processor contains billions of silicon transistors. The 2020 Apple M1 chip had 16 billion transistors on a chip smaller than your fingernail!

⚑ Interactive Periodic Table

Click any element to see its details. Colour-coded by element type.

πŸ‘† Click an element above to see its details

πŸ§ͺ Halogen Displacement Visualiser

Click each test tube to see what happens when a halogen is added to a salt solution!

πŸ‘† Click a test tube to see the reaction

πŸ“ˆ Periodic Trends Bar Charts

Select a trend to visualise. Charts animate when switching.

πŸƒ Flashcards β€” The Periodic Table

Click the card to flip it!

Answer
πŸ‘† Click card to flip

❓ Quiz β€” The Periodic Table

πŸ”’ Worked Example β€” Electronic Configuration & Periodic Position

Problem: Element X has 20 protons. Determine: its electronic configuration, group, period, the number of valence electrons, and whether it is a metal or non-metal.

Type each answer (or type show to reveal):

Step 1: Write the Electronic Configuration

Atomic number = 20 means 20 electrons. Fill shells: 2, 8, 8, then how many remain? Write it as: 2,8,8,2

Step 2: Determine the Group

The group number equals the number of valence electrons (outermost shell). From (2,8,8,2), how many electrons are in the outermost shell? What group is this?

Step 3: Determine the Period

The period number equals the number of occupied electron shells. Count the shells in (2,8,8,2).

Step 4: Metal or Non-metal?

Group II elements are always metals. They tend to LOSE electrons to form +2 ions. Is element X (Calcium) a metal or non-metal? Type one word.

πŸ”— Matching β€” Periodic Table Concepts

Click a term, then click its matching description. Green = correct!

Term

Description

πŸ“ CSEC-Style Questions

Q1. The electronic configuration of element X is (2,8,5). (a) State the group and period of X. (b) Is X a metal or non-metal? Give a reason. (c) When X reacts, does it lose or gain electrons? How many? [5 marks] +
Mark Scheme

1 (a) Group V (5 valence electrons βœ“); Period 3 (3 occupied shells βœ“)

2 (b) Non-metal βœ“ β€” it is in Group V on the right side of the periodic table, where non-metals are found. It tends to gain electrons rather than lose them. βœ“

3 (c) Gains electrons βœ“; gains 3 electrons βœ“ (to complete its outer shell to 8; 8 βˆ’ 5 = 3)

Element X is Phosphorus (P).

Q2. Explain why calcium reacts more vigorously than magnesium with dilute hydrochloric acid. [4 marks] +
Mark Scheme

1 Calcium is below magnesium in Group II. βœ“

2 Calcium has more electron shells than magnesium β†’ larger atomic radius. βœ“

3 The valence electrons in calcium are further from the nucleus and more shielded by inner shells. βœ“

4 Therefore it is easier to lose the 2 valence electrons β†’ calcium is more reactive. βœ“

Note: Must include all 4 points for full marks β€” "further from nucleus", "more shielding", "easier to lose electrons", "more reactive".

Q3. When chlorine gas is bubbled into aqueous potassium bromide solution, the solution turns orange-brown. (a) Explain why this occurs. (b) Write a balanced equation. (c) Why does bromine NOT displace chlorine from potassium chloride solution? [5 marks] +
Mark Scheme

1 (a) Chlorine is more reactive (stronger oxidising agent) than bromine. βœ“

2 Chlorine displaces bromine from the KBr solution, forming free bromine (Brβ‚‚). βœ“ The orange-brown colour is due to Brβ‚‚ being produced. βœ“

3 (b) Clβ‚‚(g) + 2KBr(aq) β†’ 2KCl(aq) + Brβ‚‚(aq) βœ“ (balanced, state symbols βœ“)

4 (c) Bromine is less reactive than chlorine (lower in Group VII, weaker oxidising agent). A less reactive element cannot displace a more reactive element. βœ“

Q4. Give THREE physical differences between sodium (a metal) and chlorine (a non-metal) found in Period 3. [3 marks] +
Mark Scheme

Any three of:

1 Sodium is a solid at room temperature; chlorine is a gas. βœ“

2 Sodium is shiny/has metallic lustre; chlorine is dull/yellow-green. βœ“

3 Sodium conducts electricity; chlorine does not (poor conductor). βœ“

4 Sodium has a high melting/boiling point; chlorine has a low melting/boiling point. βœ“

5 Sodium has a high density; chlorine has a low density. βœ“

Q5. Explain the difference between Mendeleev's periodic table and the modern periodic table. Why is the modern table considered more accurate? [4 marks] +
Mark Scheme

1 Mendeleev arranged elements in order of increasing atomic mass βœ“; the modern table uses atomic number (proton number) βœ“.

2 Using atomic mass caused some elements to be out of order (e.g. tellurium and iodine were swapped) βœ“.

3 Moseley (1914) showed that atomic number is the fundamental property that determines an element's identity. Using atomic number removes all the anomalies. βœ“

⭐ Key Concepts & Memory Aids

Position Rules

Group = valence electrons Period = occupied shells

Group II Trend

Reactivity ↑ down group Be < Mg < Ca < Sr < Ba

Group VII Trend

Reactivity ↑ up group I < Br < Cl < F

Displacement Rule

More reactive displaces less reactive Clβ‚‚ + 2KBr β†’ 2KCl + Brβ‚‚

Period 3

Metal react: Na > Mg > Al Non-metal: Cl > S > P

History Order

DΓΆbereiner β†’ Newlands β†’ Mendeleev β†’ Moseley

πŸ“š Resources