MODULE A6

Chemical Reactions

Balance equations, classify reaction types, test for gases, and understand how catalysts work — all in one place! ⚗️🔥

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1. Law of Conservation of Mass

In any chemical reaction, mass is neither created nor destroyed. The total mass of reactants equals the total mass of products.

⚖️ Why equations must be balanced: A balanced equation has the same number of each type of atom on both sides. This is just the Law of Conservation of Mass in action — you can't create or destroy atoms!

State Symbols

SymbolMeaningExample
(s)SolidNaCl(s)
(l)LiquidH₂O(l)
(g)GasCO₂(g)
(aq)Aqueous (dissolved in water)NaOH(aq)

How to Balance Equations — Step by Step

  1. Write the unbalanced equation with correct formulas
  2. Count atoms of each element on both sides
  3. Add coefficients (numbers in front of formulas) to balance — start with the most complex molecule
  4. NEVER change subscripts (numbers inside formulas) — only change coefficients
  5. Check: count all atoms again on both sides
⚠️ Common mistake: Students write H₃O instead of adjusting H₂O's coefficient. You can ONLY add numbers in front of whole formulas — never change the formula itself!

2. The Six Types of Chemical Reactions

TypePatternKey FeatureExample
Combination (Synthesis)A + B → ABTwo or more substances combine to make one product2Mg + O₂ → 2MgO
DecompositionAB → A + BOne substance breaks down into two or more products2H₂O₂ → 2H₂O + O₂
DisplacementA + BC → AC + BMore reactive element displaces less reactive from compoundZn + CuSO₄ → ZnSO₄ + Cu
Double DecompositionAB + CD → AD + CBTwo ionic compounds swap partners — often forms precipitateAgNO₃ + NaCl → AgCl↓ + NaNO₃
NeutralisationAcid + Base → Salt + WaterAcid and base react to form salt and waterHCl + NaOH → NaCl + H₂O
CombustionFuel + O₂ → CO₂ + H₂ORapid reaction with oxygen, releases heat and lightCH₄ + 2O₂ → CO₂ + 2H₂O
🔥 Combustion types: Complete combustion (excess O₂) → CO₂ + H₂O only. Incomplete combustion (limited O₂) → also produces CO (carbon monoxide, toxic!) and C (soot/smoke).

3. Key Equations to Know

ReactionBalanced EquationType
Magnesium burning2Mg(s) + O₂(g) → 2MgO(s)Combination
Hydrogen peroxide decomposition2H₂O₂(aq) → 2H₂O(l) + O₂(g)Decomposition
Zinc + copper sulfateZn(s) + CuSO₄(aq) → ZnSO₄(aq) + Cu(s)Displacement
Silver nitrate + sodium chlorideAgNO₃(aq) + NaCl(aq) → AgCl(s)↓ + NaNO₃(aq)Double decomposition (ppt)
Neutralisation (HCl/NaOH)HCl(aq) + NaOH(aq) → NaCl(aq) + H₂O(l)Neutralisation
Complete combustion of methaneCH₄(g) + 2O₂(g) → CO₂(g) + 2H₂O(g)Combustion
Calcium carbonate decompositionCaCO₃(s) → CaO(s) + CO₂(g)Decomposition
Iron + steam3Fe(s) + 4H₂O(g) → Fe₃O₄(s) + 4H₂(g)Displacement

4. Gas Tests

GasFormulaTestPositive Result
HydrogenH₂Apply a lit splintSqueaky pop
OxygenO₂Apply a glowing splintSplint relights
Carbon dioxideCO₂Bubble through limewater (Ca(OH)₂)Turns milky/cloudy
AmmoniaNH₃Damp red litmus paperTurns blue (only alkaline gas)
ChlorineCl₂Damp blue litmus paperTurns red then bleaches white
Sulfur dioxideSO₂Acidified potassium dichromateOrange → green
Hydrogen chlorideHClHold near ammoniaWhite fumes (NH₄Cl)

5. Catalysts

A catalyst is a substance that increases the rate of a chemical reaction without being used up (consumed) in the reaction. It works by providing an alternative pathway with a lower activation energy.

CatalystReaction it Speeds UpIndustry/Use
Iron (Fe)N₂ + 3H₂ ⇌ 2NH₃ (Haber Process)Fertiliser production
Manganese(IV) oxide (MnO₂)2H₂O₂ → 2H₂O + O₂Lab preparation of O₂
Platinum (Pt) / RhodiumCar exhaust catalytic converterReduces CO, NOₓ emissions
Enzymes (biological)Fermentation: C₆H₁₂O₆ → 2C₂H₅OH + 2CO₂Brewing, bread-making
Vanadium pentoxide (V₂O₅)2SO₂ + O₂ → 2SO₃ (Contact Process)Sulfuric acid manufacture

6. Reversible Reactions and Equilibrium

Some reactions can go in both directions and are called reversible reactions, shown by the symbol ⇌. When the rate of the forward reaction equals the rate of the reverse reaction, dynamic equilibrium is reached.

⇌ Example: N₂(g) + 3H₂(g) ⇌ 2NH₃(g) (Haber Process)
At equilibrium: both forward and reverse reactions still occur, but at the same rate. Concentrations of all species remain constant (not necessarily equal).

Precipitation Reactions

When two aqueous solutions are mixed and an insoluble solid forms, this is called a precipitate (shown by ↓). This is a type of double decomposition.

Reactants MixedPrecipitate FormedColour
AgNO₃(aq) + NaCl(aq)AgCl(s) ↓White
BaCl₂(aq) + Na₂SO₄(aq)BaSO₄(s) ↓White
Pb(NO₃)₂(aq) + KI(aq)PbI₂(s) ↓Yellow
FeCl₃(aq) + NaOH(aq)Fe(OH)₃(s) ↓Rust-brown
CuSO₄(aq) + NaOH(aq)Cu(OH)₂(s) ↓Blue

⚡ Interactive Equation Balancer

Click the + and buttons to adjust coefficients and balance each equation. Get all atom counts equal to win! 🎯

🧪 Gas Test Simulator

Click each gas to see the test procedure, observation, and result. These are must-know tests for CSEC!

👆 Click a gas above to see its test

📈 Reaction Types — Frequency Chart & Properties

An overview of the 6 reaction types with their key properties visualised.

🃏 Flashcards — Chemical Reactions

Click the card to flip!

Answer
👆 Click card to flip

❓ Quiz — Chemical Reactions

🔢 Worked Example — Balancing an Equation Step by Step

Problem: Balance the equation for aluminium reacting with hydrochloric acid:
Al + HCl → AlCl₃ + H₂

Type each answer (or type show to reveal):

Step 1: Count atoms on each side (unbalanced)

In the unbalanced equation Al + HCl → AlCl₃ + H₂, how many Cl atoms are on the RIGHT side (in AlCl₃)?

Step 2: Balance Cl by adjusting HCl

We need 3 Cl on the left to match 3 Cl in AlCl₃. What coefficient goes in front of HCl?

Step 3: Balance H

Now we have Al + 3HCl → AlCl₃ + H₂. Left: 3 H (from 3HCl). Right: 2 H (from H₂). To get 6 H on both sides, what coefficient goes in front of H₂?

Step 4: Write the final balanced equation

Multiply everything by 2 to remove the fraction: 2Al + 6HCl → 2AlCl₃ + 3H₂. Verify: Al (2=2 ✓), H (6=6 ✓), Cl (6=6 ✓). What type of reaction is this?

🔗 Matching — Reactions & Gas Tests

Click a term, then its matching description. Green = correct!

Term / Gas

Test / Definition

📝 CSEC-Style Questions

Q1. Balance the following equations and state the type of reaction in each case: (a) __ Fe + __ O₂ → __ Fe₂O₃ (b) __ Ca + __ H₂O → __ Ca(OH)₂ + __ H₂ [6 marks]+
Mark Scheme

1 (a) 4Fe + 3O₂ → 2Fe₂O₃ ✓ (check: Fe: 4=4, O: 6=6). Type: Combination (Synthesis)

2 (b) Ca + 2H₂O → Ca(OH)₂ + H₂ ✓ (check: Ca:1=1, H:4=4, O:2=2). Type: Displacement ✓ (Ca displaces H from H₂O)

Award 1 mark per correct balanced equation (2 marks), 1 mark per state symbols if present (2 marks), 1 mark per reaction type (2 marks).

Q2. Describe the test for each of the following gases and state the positive result: (a) hydrogen, (b) carbon dioxide, (c) ammonia. [6 marks]+
Mark Scheme

1 (a) Hydrogen: Hold a lit splint near the mouth of the tube. ✓ Positive result: a squeaky "pop" sound. ✓

2 (b) Carbon dioxide: Bubble the gas through limewater (calcium hydroxide solution). ✓ Positive result: the limewater turns milky/cloudy. ✓ (CaCO₃ precipitate forms: Ca(OH)₂ + CO₂ → CaCO₃↓ + H₂O)

3 (c) Ammonia: Hold damp red litmus paper in the gas. ✓ Positive result: the paper turns blue. ✓ (NH₃ is the only common alkaline gas)

Q3. Zinc is added to copper sulfate solution. (a) Write a balanced equation. (b) State the type of reaction. (c) Describe what you would observe. (d) Explain why this reaction occurs. [5 marks]+
Mark Scheme

1 (a) Zn(s) + CuSO₄(aq) → ZnSO₄(aq) + Cu(s) ✓

2 (b) Displacement reaction ✓

3 (c) The blue colour of the solution fades (as Cu²⁺ is used up). ✓ A reddish-brown/pink solid (copper) is deposited on the zinc. ✓

4 (d) Zinc is higher in the reactivity series than copper, so zinc can displace copper from its salt solution. ✓

Q4. (a) Define a catalyst. (b) Name the catalyst used in the Haber Process. (c) Write the balanced equation for the Haber Process. (d) Explain how a catalyst increases the rate of reaction without being used up. [5 marks]+
Mark Scheme

1 (a) A catalyst is a substance that increases the rate of a reaction without being consumed (used up) in the reaction. ✓

2 (b) Iron (Fe) ✓

3 (c) N₂(g) + 3H₂(g) ⇌ 2NH₃(g) ✓ (accept without state symbols; reversible arrow needed for full mark)

4 (d) The catalyst provides an alternative reaction pathway with a lower activation energy ✓ so more particles have enough energy to react. ✓ The catalyst participates in the reaction but is regenerated at the end — it ends up unchanged. ✓

Q5. Two solutions, lead(II) nitrate and potassium iodide, are mixed. (a) Name the type of reaction that occurs. (b) Write a balanced equation including state symbols. (c) State what you would observe. [4 marks]+
Mark Scheme

1 (a) Double decomposition (precipitation reaction) ✓

2 (b) Pb(NO₃)₂(aq) + 2KI(aq) → PbI₂(s) + 2KNO₃(aq) ✓ (balanced ✓, state symbols ✓)

3 (c) A yellow precipitate (lead iodide, PbI₂) forms immediately when the solutions are mixed. ✓

⭐ Key Equations & Concepts

Conservation of Mass

mass reactants = mass products Balance by changing coefficients only

6 Reaction Types

Combination · Decomposition Displacement · Double Decomp. Neutralisation · Combustion

Gas Tests (Memory Aid)

H₂: squeaky pop 💥 O₂: relights splint 🔥 CO₂: milky limewater ☁️ NH₃: litmus → blue 🔵

Precipitate Colours

AgCl ↓ = white BaSO₄ ↓ = white PbI₂ ↓ = yellow Cu(OH)₂ ↓ = blue

Key Catalysts

Fe → Haber (NH₃) MnO₂ → H₂O₂ decomp. V₂O₅ → Contact (H₂SO₄)

State Symbols

(s) solid · (l) liquid (g) gas · (aq) aqueous ↓ precipitate · ↑ gas given off

📚 Resources